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.........
checking whether to enable LIBXML support... yes
checking libxml2 install dir... /usr/local
checking for xml2-config path...
configure: error: xml2-config not found. Please check your libxml2 installation.
===> Script "configure" failed unexpectedly.
Please report the problem to ale@FreeBSD.org [maintainer] and attach the
"/usr/ports/lang/php5/work/php-5.3.2/config.log" including the output of the
failure of your make command. Also, it might be a good idea to provide an
overview of all packages installed on your system (e.g. an `ls /var/db/pkg`).
*** Error code 1

Stop in /usr/ports/lang/php5.